|Douglas Muir 406|
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What do you think of a Cleric using either the Law or Evil Domain to snag the Subdomain Devil. That would get you Planar Binding as a 6th level spell the same as Wizards, thus bypassing one of the significant issues of a Divine caster even though it limits you to only Devils (and of note that would also open up the Fiendish Vessel archetype which gets you rather nice thematic abilities if you're a Tiefling).
I'm neutral about Fiendish Vessel -- it's thematically quite nice, but you already get an imp from being a Diabolist, and the ability to evilbomb good foes is very situational. (You can use the imp familiar to do it, but unlike your imp companion, those things cost money to replace.) Also, you have to be a tiefling, and while there are a couple of tiefling subraces that are good for a diabolist (grimspawn and beastbrood), they're IMO not quite as good a human, elf, gnome (for a sorceror) or some of the aasimar subraces. That said, this is a thematic choice that is perfectly playable. If you go this route, consider the Dark Magic Affinity and Family Connections tiefling traits -- both are great for a Diabolist -- and once you have 9,000 gp to spare, invest in a Darksire Amulet.
Taking the devil subdomain is probably the best thing to do for a cleric, yes. Planar Binding is great at 11th and 12th levels, okay at 13th and 14th levels. Then it starts to fade, but at that point you'll have Greater Planar Ally and the cost/benefit equation will be starting to tip in your direction.
I'm looking at making one for a hopefully upcoming campaign and whilst I really like the PrC and a Wizard seems the best choice I think a Cleric opens up some super fun options (especially things such as Conversion Channel, who doesn't love making good guys choose between death or converting to Asmodeus!)
I agree -- that's a hugely fun feat. Mechanically it's limited by the fact that your Diabolist levels don't give you channeling dice, but who cares? Being able to healbomb once/day is also pretty nice.